Thermal stability of polarization structures in corona-charged P(VDF-HFP) copolymer films

Y. Gorokhovatsky, V.G. Boitzov, D. Rychkov
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引用次数: 1

Abstract

The trapping of charge carriers in localized states on the surface of /spl beta/-crystallites in P(VDF-HFP) films has been studied by means of a novel voltage recovery technique. It has been found that a phase transition from /spl alpha/-non polar to the /spl delta/-polar configuration takes place under the process of charge injection. Using experimental measurements and appropriate analysis, we determine the energy distribution of the traps located near the /spl beta/-crystallites surfaces, and estimate the spatial dimensions of the molecular dipoles to be about 11-12 nm. The industrial application method was suggested in order to improve the thermal stability of charge and polarization in corona-charged copolymer films.
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电晕带电P(VDF-HFP)共聚物薄膜极化结构的热稳定性
利用一种新的电压恢复技术研究了P(VDF-HFP)薄膜中/spl β /-晶体表面定域载流子的俘获。发现在电荷注入过程中发生了从/spl α /-非极性到/spl δ /-极性的相变。通过实验测量和适当的分析,我们确定了位于/spl β /-晶体表面附近的陷阱的能量分布,并估计了分子偶极子的空间尺寸约为11-12 nm。为了提高电晕带电共聚物薄膜的电荷和极化热稳定性,提出了工业应用的方法。
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