Dielectric study of (alcohol)/sub x/(water)/sub 1-x/ mixtures and valuation of static permittivity and relaxation time for supercooled water

G. Noyel, L. Jorat, J. Huck, O. Derriche
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引用次数: 2

Abstract

Results are presented which lead to the characterization of (alcohol)/sub x/(water)/sub 1-x/ mixtures between ambient and glass temperature over the whole molar fraction range. Suitable extrapolations to zero alcohol concentration allow one to calculate the dielectric relaxation time and the static permittivity of supercooled water below its homogeneous nucleation temperature. Use is made of a dielectric relaxation spectrometer operating from 1 MHz to 10 MHz in the temperature range -200, +100 degrees C and a total influence cell. The results obtained confirm that supercooled water dielectric parameters down to T/sub g/, are independent of alcohol.<>
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(酒精)/亚x/(水)/亚1-x/混合物的介电研究及过冷水的静态介电常数和弛豫时间的计算
给出了在整个摩尔分数范围内环境温度和玻璃温度之间的(酒精)/亚x/(水)/亚1-x/混合物的表征结果。适当的外推到零酒精浓度允许人们计算介电松弛时间和过冷水的静态介电常数低于其均匀成核温度。使用介电弛豫光谱仪,工作频率为1 MHz至10 MHz,温度范围为-200、+100℃,使用总影响池。结果证实,过冷水介电参数低至T/sub g/,与乙醇无关
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