Use of Lysimeters to Evaluate the Atrazine Dynamics in Soil Cultivated With Maize

A. C. G. Júnior, Elio Conradi Junior, Jéssica Manfrin, D. Schwantes, Juliano Zimmermann, Guilherme Lindner Ziemer, Marcelo Ângelo Campagnolo, A. Schiller
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Abstract

Despite the numerous studies reporting about pesticide interactions in inumerous environmental conditions, there is insufficient information relating their dynamics to the various textural classes of Brazilian soils and, consequently, the environmental problems caused by the use and application of these compounds. In this way, the objective of this study was to evaluate the atrazine dynamics through determination of the surface runoff and percolation in a Red Latosol cultivated with maize, through studies delineated in drainage lysimeter. Applications of atrazine at the recommended doses were performed weekly up to 44 days after emergence of the maize. Rainfall simulations (150 mm) were performed 24 and 48 h after each application, collecting samples of runoff and percolated water at intervals of 5 min. The samples were sent to the laboratory for analysis of physical and chemical attributes and determination of atrazine concentrations by GC-ECD. Concentrations above the maximum values allowed by the regulatory agencies were found in approximately 99.16% of the obtained samples. The presence of atrazine in runoff and percolated water was recorded. Until 30 days after emergence (DAE) of the crop, higher concentrations of the pesticide were observed in the runoff 24 h after application, mainly in the initial collection minutes. In the percolated samples high concentrations of the pesticide were found even with the development of the crop, however, usually being smaller to those observed for surface runoff. There was a good correlation between the GUS (Groundwater Ubiquity Score) index and the GOSS model and the results obtained. It is concluded that there is the possibility of transporting atrazine in surface runoff and percolation in the different phenological stages of the maize crop when submitted to sequential applications and under high precipitation conditions.
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用溶液计评价玉米栽培土壤中莠去津的动态
尽管有许多研究报告了农药在各种环境条件下的相互作用,但它们的动态与巴西土壤的各种质地类别有关的信息不足,因此,这些化合物的使用和应用造成的环境问题也不充分。这样,本研究的目的是通过测定种植玉米的红红壤的地表径流和渗滤,通过排水渗滤仪描绘的研究来评估阿特拉津的动态。按推荐剂量每周施用阿特拉津,直至玉米出苗后44天。在每次施用后24和48 h进行降雨模拟(150 mm),每隔5分钟收集径流和渗透水样品。样品被送到实验室进行物理和化学属性分析,并通过GC-ECD测定阿特拉津浓度。在获得的样品中,大约99.16%的浓度高于监管机构允许的最大值。记录了径流和渗透水中阿特拉津的存在。直到作物出苗后30天,在施用后24 h,主要是在最初的收集分钟内,在径流中观察到较高的农药浓度。在渗透样品中发现,即使随着作物的生长,农药浓度也很高,但通常比地表径流中观察到的浓度要小。GUS (Groundwater Ubiquity Score)指数与GOSS模型及所得结果具有较好的相关性。结果表明,在连续施用和高降水条件下,阿特拉津在玉米作物不同物候阶段有可能通过地表径流和渗流进行转运。
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