Thermodynamics of the Fermi gas in a nanotube

Y. Poluektov, A. Soroka
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Abstract

For the ideal Fermi gas that fills the space inside a cylindrical tube, there are calculated the thermodynamic characteristics in general form for arbitrary temperatures, namely: the thermodynamic potential, energy, entropy, equations of state, heat capacities and compressibilities. All these quantities are expressed through the introduced standard functions and their derivatives. The radius of the tube is considered as an additional thermodynamic variable. It is shown that at low temperatures in the quasi-one-dimensional case the temperature dependencies of the entropy and heat capacities remain linear. The dependencies of the entropy and heat capacities on the chemical potential have sharp maximums at the points where the filling of a new discrete level begins. The character of dependencies of thermodynamic quantities on the tube radius proves to be qualitatively different in the cases of fixed linear and fixed total density. At the fixed linear density these dependencies are monotonous and at the fixed total density they have an oscillating character. Key words: Fermi particle, nanotube, thermodynamic functions, low-dimensional systems, equation of state, heat capacity, compressibility
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纳米管中费米气体的热力学
对于填充圆柱管内空间的理想费米气体,计算了其在任意温度下的一般热力学特性,即:热力学势、能量、熵、状态方程、热容和可压缩性。所有这些量都通过引入的标准函数及其导数来表示。管的半径被认为是一个附加的热力学变量。结果表明,在准一维低温情况下,熵和热容的温度依赖关系保持线性。熵和热容对化学势的依赖性在新的离散能级开始填充的地方有明显的最大值。在固定线密度和固定总密度的情况下,热力学量对管半径的依赖特性在性质上是不同的。在固定的线性密度下,这些依赖关系是单调的,在固定的总密度下,它们具有振荡特征。关键词:费米粒子,纳米管,热力学函数,低维系统,状态方程,热容,可压缩性
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