Plasma Diagnostics using Cavity Ringdown Spectroscopy Combined with Optical Emission Spectroscopy

C. Wang, Y. Duan, T. Dibble
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Abstract

Cavity ringdown spectroscopy (CRDS) is a sensitive absorption spectral technique and capable of measuring absolution concentration of species in a variety of environments. In recent years, CRDS has been increasingly applied for plasma diagnostics. Through measurements of high resolution spectral linewidths of selected species, plasma gas kinetic temperature and electron density profiles can be determined from the lineshape broaden components (Lorentzian and Doppler components). Determination of the distribution of particular chemical species, such as transient radicals, can help understand plasma associated chemistry. Plasma thermo-equilibrium status can be evaluated by simultaneously analyzing ringdown-based absorption and optical emission spectra of a diagnostic agent in the plasma. This talk presents three powerful approaches for plasma diagnostics: analysis of linewidth broadening of selected optical transitions, determination of density distribution profile of chemical species, and simultaneous measurements of absorption and emission spectra. Additionally, the advantages and challenging issues of CRDS for plasma diagnostics will be discussed.
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使用腔衰荡光谱与光学发射光谱相结合的等离子体诊断
腔衰荡光谱(CRDS)是一种灵敏的吸收光谱技术,能够测量各种环境下物种的绝对浓度。近年来,CRDS在血浆诊断中的应用越来越广泛。通过测量所选物质的高分辨率谱线宽度,可以从谱线宽度分量(洛伦兹分量和多普勒分量)确定等离子体气体的动力学温度和电子密度分布。确定特定化学物质的分布,如瞬态自由基,可以帮助理解等离子体相关化学。等离子体热平衡状态可以通过同时分析等离子体中诊断试剂的环衰吸收光谱和光发射光谱来评估。本讲座介绍了等离子体诊断的三种强有力的方法:分析选定的光学跃迁的线宽加宽,确定化学物质的密度分布曲线,以及同时测量吸收和发射光谱。此外,还将讨论CRDS用于血浆诊断的优势和面临的挑战。
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