Synthesis and Characterization of New Triazols Derivatives as C-Steel Reducing of Corrosion in Acidic Medium

May Jaleel Abed, Ahmed Ebrahim Hamzah, K. K. Alasedi
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Abstract

Six derivatives of novel triazoles were produced from some substituted benzoic acid with thiocarbazide via method of grinding. The produced Chemicals were described via 1HNMR, IR, and 13CNMR spectra examinations. Produced derivatives of C2H3N3 were examined and assessed as reducing of corrosion in 0.5 M HCl for low-C steel utilizing procedure of losing weight. It was noticed that such chemicals had an encouraging act as reducer counter to mild steel corrosion of in solution being acidic. Reducing of maximum action was assessed at various concentrations and temperature of effector. Competence of corrosion reducer surpassed 96%. The exceptional action was due to inhibitor films adsorption development on surfacing steel. Reducing adsorption on surface of steel tracked Langmuir adsorption isotherm (LAI). The results were long-established BY theoretical calculations of quantum chemistry.
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新型三氮唑类c -钢衍生物的合成与表征
以取代苯甲酸和硫脲为原料,采用研磨法制备了6个新型三唑衍生物。生成的化学物质通过1HNMR, IR和13CNMR光谱检查进行了描述。采用减重法对生产的C2H3N3衍生物在0.5 M HCl中对低碳钢的缓蚀性能进行了检测和评价。在酸性溶液中对低碳钢的腐蚀有还原剂的促进作用。考察了不同浓度和温度下效应剂的最大作用降低率。减蚀剂合格率达96%以上。这种特殊的作用是由于表面钢的抑制剂膜的吸附发展。钢表面的还原性吸附跟踪Langmuir吸附等温线(LAI)。这些结果早已被量子化学的理论计算所证实。
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