Raman structural study of random olefin copolymers

ALT Proceedings Pub Date : 2012-11-01 DOI:10.12684/ALT.1.80
Yu.V. Zavgorodnev, K. Prokhorov, G. Y. Nikolaeva, E. Sagitova, P. Pashinin, A. Kovalchuk, A. N. Klyamkina, P. M. Nedorezova, L. Novokshonova, T. Ushakova, E. Starchak, B. F. Shklyaruk, M. Guseva, P. Donfack, A. Materny
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Abstract

In this work we present Raman study of random copolymers of ethylene and propylene with a number of α-olefins, and investigation of the relationships between the spectral characteristics of the Raman lines and the copolymer structural properties. For both the copolymers we observed rapid decrease in the crystallinity and conformational order as the content of the incorporated monomer increases.
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无规烯烃共聚物的拉曼结构研究
本文对乙烯和丙烯与若干α-烯烃的无规共聚物进行了拉曼研究,并研究了拉曼谱线的光谱特征与共聚物结构性质之间的关系。对于这两种共聚物,我们观察到随着加入单体含量的增加,结晶度和构象顺序迅速下降。
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