Ceramic-metal composite to recover the bulk property of ceramic powder

Kai Wu, Yonghong Cheng, Xiaolin Chen
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Abstract

An interval percolation model was put forward to describe the ceramic-metal composite, in which the contact resistance of ceramic powder was reduced so that the bulk property of the ceramic could be recovered. Monte-Carlo simulation confirmed that the bulk property can be surely recovered in a cubic network if the fraction of conductive sites is in the range of 0.101 to 0.311. Experimental works also indicated that the bulk property of positive temperature coefficient (PTC) of BaTiO3 was recovered after the mixture of the BaTiO3 ceramic powder and silver ink was baked. Moreover, it was shown that the percolation threshold decreased with the increase of the size of ceramic particles, and the PTC bulk property appeared more obviously at higher electrical field. This may provide a new way for the polymer/ceramic composite.
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利用陶瓷-金属复合材料恢复陶瓷粉末的体积特性
提出了一种区间渗透模型来描述陶瓷-金属复合材料,该模型可以降低陶瓷粉末的接触电阻,从而恢复陶瓷的整体性能。Monte-Carlo模拟证实,当导电位点的分数在0.101 ~ 0.311范围内时,在立方网络中可以确定地恢复块体性质。实验还表明,将BaTiO3陶瓷粉与银墨混合后进行烘烤,恢复了BaTiO3正温度系数(PTC)的体积性质。随着陶瓷颗粒尺寸的增大,PTC的渗透阈值逐渐降低,且电场越大,PTC的体化性能越明显。这为聚合物/陶瓷复合材料的研究提供了一条新的途径。
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