Investigation of moisture absorption rate and diffusivity of plant fibre-reinforced composites

Obi LE, Uwanugo R.G. Uchejiora
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Abstract

This research investigated the moisture absorption rate and diffusivity of plant Fibers-reinforced-composites; using bamboo fiber, raffia and coconut fibers through laboratory experimental investigations. The major limitation of using natural fibers in durable composite applications are their high moisture absorption and poor dimensional stability (swelling); and this swelling of fibers causes micro-cracking and degradation of the composites. In this investigation, the fibers were treated with sodium hydroxide (NaOH) chemical and acetylation to decrease the hydroxyl group in the fibers. Experimental results reveal that the moisture absorption and degree of swelling of the treated bamboo raffia and coconut fiber composites are 25 - 35% lower than those of composites produced with untreated bamboo, raffia and coconut fibers. Experimental results also show that strong intermolecular fiber-matrix bonding decreases the rate of moisture absorption in bio-composites. The diffusivity of the bamboo, raffia and coconut fibers-reinforced-composites for 24hrs at 1000C were experimentally measured to be 4.91, 3.33, and 3.94 mm2/sec respectively. The results showed that when these fiber plant materials are treated with sodium hydroxide (NaON) the diffusivity rate of the fiber reinforced composite material is brought under considerable control and its dimensional stability immensely enhanced though improved strong intermolecular fiber-matrix bonding and the reduction of swelling.
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植物纤维增强复合材料吸湿率和扩散率的研究
研究了植物纤维增强复合材料的吸湿率和扩散率;采用竹纤维、烟叶纤维和椰子纤维进行实验室实验研究。在耐用复合材料应用中使用天然纤维的主要限制是它们的高吸湿性和较差的尺寸稳定性(膨胀);纤维的膨胀会导致复合材料的微裂和降解。采用氢氧化钠(NaOH)化学处理和乙酰化处理来降低纤维中的羟基。实验结果表明,经处理的竹叶、椰子纤维复合材料的吸湿性和膨胀度比未经处理的竹叶、椰子纤维复合材料低25 ~ 35%。实验结果还表明,强分子间纤维-基质结合降低了生物复合材料的吸湿率。实验测定了竹纤维、烟叶纤维和椰子纤维增强复合材料在1000℃下24h的扩散系数分别为4.91、3.33和3.94 mm2/sec。结果表明,用氢氧化钠(NaON)处理这些植物纤维材料后,纤维增强复合材料的扩散率得到了很大的控制,通过增强纤维-基质之间的强结合和减少膨胀,大大提高了材料的尺寸稳定性。
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