Studying the Photocatalytic Activity of Iron Oxides Synthesized by Plasma Dynamic Method

I. Shanenkov, A. Ivashutenko, A. Sivkov, Y. Vympina, Y. Shanenkova, A. Tsimmerman
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Abstract

Photoelectrochemical water splitting is an actively developed area of hydrogen energy. It requires the use of highly-active photocatalysts, one of the most promising of which is a-Fe2O3 iron oxide. Among all iron oxides modifications, another phase f:-Fe2O3 can be potentially used as photocatalysts. However, this phase is difficult to be obtained by most of the known methods. In this work, the plasma dynamic synthesis method is used to obtain both of these phases to study their photocatalytic activity. For this, the synthesis system is improved to reach as highest yield of pointed phases as possible. The obtained nanosized powders with a predominant content of α- Fe2O3 and f:-Fe2O3 are studied with a three-electrode cell method. Both phases show the quite similar catalytic activity and a high stability.
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等离子体动力学法制备氧化铁的光催化活性研究
光电化学水分解是氢能的一个积极发展的领域。它需要使用高活性的光催化剂,其中最有前途的是a-Fe2O3氧化铁。在所有的氧化铁改性中,另一种相f:-Fe2O3有可能用作光催化剂。然而,这一相很难用大多数已知的方法得到。本文采用等离子体动态合成的方法合成了这两种相,研究了它们的光催化活性。为此,对合成体系进行了改进,以达到尽可能高的点相收率。用三电极电池法对制备的以α- Fe2O3和f:-Fe2O3为主的纳米粉体进行了研究。两相具有相当的催化活性和较高的稳定性。
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