Mechanisms and Mitigation Strategies of Iron Sulfide Deposition in Sour Gas Wells

Tao Chen, Qiwei Wang, F. Chang
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Abstract

Iron sulfide deposition on downhole tubular is a ubiquitous phenomenon in sour gas wells, especially for these producing from high temperature and high pressure (HTHP) reservoirs. Many studies have been focused on iron sulfide formation and mitigation previously, the root-cause of iron sulfide deposition is still not well defined and the cost-effective scale management strategy is remained to be identified. This paper presents some new progresses made for understanding the mechanisms of iron sulfide deposition in the sour gas wells, using a combined approach of laboratorial tests and model prediction. Study results indicate that iron sulfide can deposit during both acidizing treatment and production stage. Large amount of iron sulfide could precipitate during acidizing treatment and potentially causes severe formation damage. During production stage iron sulfide is accumulated on tubular surface due to corrosion of the underlying metal. This paper presents a fundamental study to understand the mechanisms of iron sulfide deposition in sour gas wells. Corrosion and scaling inhibition are recommended to mitigate iron sulfide deposition in sour gas wells, especially during acidizing treatment.
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含硫气井中硫化铁沉积机理及缓解策略
在含硫气井中,尤其是高温高压气藏中,井下管状硫化铁沉积是一个普遍存在的现象。以前的许多研究都集中在硫化铁的形成和缓解上,硫化铁沉积的根本原因仍然没有很好地确定,成本效益的规模管理策略仍有待确定。本文介绍了利用实验室试验与模型预测相结合的方法,在认识含硫气井硫化铁沉积机理方面取得的一些新进展。研究结果表明,在酸化处理和生产阶段均有硫化铁沉积。酸化处理过程中会析出大量的硫化铁,可能会对地层造成严重的损害。在生产阶段,由于下伏金属的腐蚀,硫化铁在管材表面积累。本文为了解含硫气井中硫化铁沉积机理进行了基础性研究。建议采用缓蚀剂和阻垢剂来减缓含硫气井中硫化铁的沉积,特别是在酸化处理过程中。
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