The electrical conduction in polyimide nanocomposites

Y. Cao, P. Irwin
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引用次数: 53

Abstract

The electrical properties of polyimide based nanocomposites were fully investigated by isothermal steady-state current, dielectric spectroscopy, and thermally stimulated current measurements. The effect of nano fillers on the dielectric properties was evaluated via the interfacial polarization as well as the electrical conduction mechanism study. The electrical conduction of polyimide nanocomposites is found to be thermally assisted ionic in nature. The shift of the main thermally stimulated current peak to higher temperatures indicates deeper trapping by incorporating nano fillers. As a result, the nanocomposites will at least maintain the electrical breakdown strength because of the reduced electrical conductivity at elevated temperatures.
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聚酰亚胺纳米复合材料的导电性
通过等温稳态电流、介电光谱和热刺激电流测量,对聚酰亚胺基纳米复合材料的电学性能进行了全面研究。通过界面极化和导电机理研究,评价了纳米填料对介电性能的影响。聚酰亚胺纳米复合材料的导电本质上是热辅助离子导电。主要的热刺激电流峰向更高温度的移动表明,通过加入纳米填料,捕获更深。因此,由于在高温下电导率降低,纳米复合材料将至少保持电击穿强度。
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