Spectrophotometric Analysis UV-VIS Irradiated Ternary Hybrid PMMA Composite

R. Al-Khafaji, Rusul Taha Hussein
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引用次数: 1

Abstract

Ternary hybrid composite PMMA matrix with TiO2-Al2O3- ZrO2 as additives were prepared carried out casting method. Range of weight fractions (92-84 wt %) of PMMA, fixed percentage (4%) of TiO2 and range of weight fractions (4-12 wt %) of Al2O3 and ZrO2 were used as started materials. Optical constants were obtained of the prepared samples using spectrometer (UV- VIS). Absorption coefficient, extinction coefficient, refractive index and optical energy gap were calculated. It was noticing of absorption coefficient and extinction coefficient and refractive index values for (PMMA - TiO2- Al2O3) higher than that of (PMMA - TiO2- ZrO2), also, more decreasing optical energy gap values in the first composites than other samples.
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紫外-可见辐照三元杂化PMMA复合材料的分光光度分析
采用铸造法制备了以TiO2-Al2O3- ZrO2为添加剂的三元杂化复合PMMA基体。以一定重量分数(92-84 wt %)的PMMA、一定重量分数(4%)的TiO2和一定重量分数(4-12 wt %)的Al2O3和ZrO2作为起始材料。用紫外-可见光谱法测定了样品的光学常数。计算了吸收系数、消光系数、折射率和光能隙。(PMMA - TiO2- Al2O3)的吸收系数、消光系数和折射率值均高于(PMMA - TiO2- ZrO2),且第一种复合材料的光能隙值下降幅度大于其他样品。
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