DCG holograms as nanosized composite film elements

P. Sharlandjiev, B. Markova
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Abstract

It is well known that dichromated gelatin is one of the best materials for phase hologram recording. Several competing hypotheses for the nature ofthe photoinduced response in DCG have been discussed in the literature, and still there is no generally accepted point of view. Recently we have demonstrated how the optical response of DCG holograms can be analyzed on the basis of light scattering from nano-voids, which appear in the process of hologram formation. We have assumed that the voids are ellipsoids with dimensions of 10 - 40 nm, i.e. we are within the approximations of Raleigh scattering. Here, we analyze the DCG reflection hologram performance in terms of rigorous theory of light scattering with no limitations for the size of the voids. Mathematical simulations of the reflection spectra give a plausible quantitative explanation of many experimental facts related to DCG holograms obtained by the so-called 'drastic' chemical treatment after exposure.
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作为纳米复合薄膜元件的DCG全息图
众所周知,重铬酸盐明胶是相全息记录的最佳材料之一。关于DCG中光致反应的性质,文献中已经讨论了几个相互竞争的假设,但仍然没有一个普遍接受的观点。最近,我们展示了如何利用全息图形成过程中出现的纳米空洞的光散射来分析DCG全息图的光学响应。我们假设空洞是尺寸为10 - 40纳米的椭球体,即我们在罗利散射的近似范围内。本文从严格的光散射理论出发,在不受空洞尺寸限制的情况下,分析了DCG反射全息图的性能。反射光谱的数学模拟给出了与曝光后所谓的“剧烈”化学处理获得的DCG全息图有关的许多实验事实的合理定量解释。
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