Influence of the thermal treatment applied to PAN gel on its length change and generated force

H. Tamagawa, F. Nogata, Toyotaka Watanabe, A. Abe, S. Popovic
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Abstract

PAN gel is known for its strong matrix as well as for its fast length change by the acid-base environmental solution exchange. Besides, PAN gel is a quite soft material like a real cell. Therefore it's been regarded as a most promising material as an artificial muscle. However, its matrix strength declines extremely unfortunately in basic solution. Its matrix should be improved so as not decline, otherwise it cannot be an artificial muscle for practical use. We applied a high temperature thermal treatment and a subsequent hydrolysis to PAN gel prepared through the nearly conventional processing method, and we investigated the time dependence of its length change ratio and generated force through the acid-base solution exchange, and its durability. Although its length change and force generation performances were impaired to some extent, we found an improvement of its matrix robustness and durability.
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热处理对聚丙烯腈凝胶长度变化及生成力的影响
聚丙烯腈凝胶以其强基质和在酸碱环境溶液交换中长度变化快而闻名。此外,聚丙烯腈凝胶是一种非常柔软的材料,就像真正的细胞一样。因此,它被认为是一种最有前途的人造肌肉材料。但在碱性溶液中,其基体强度急剧下降。对其基质进行改良,不使其退化,否则不能成为实用的人造肌肉。我们通过高温热处理和随后的水解制备了PAN凝胶,我们研究了其长度变化率和通过酸碱溶液交换产生的力的时间依赖性,以及它的耐久性。虽然它的长度变化和力生成性能受到一定程度的影响,但我们发现它的矩阵鲁棒性和耐久性得到了改善。
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