Synthesis, Characterization and Efficient Photocatalytic Activity of Hydrothermally Synthesized SnO2 Nanosheets

V. M. Vinosel, S. Anand, S. Pauline
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Abstract

A systematic investigation on the preparation of SnO2 nanosheets using cost effective hydrothermal method was studied. Tetragonal phase SnO2 were synthesized using tin(II)chloride dihydarte and sodium hydroxide as precursor solution with basic water mixing. The synthesized samples were examined by XRD, HRSEM, EDAX, FTIR and UV-visible spectroscopy. The nanocrystalline size and strain of the SnO2 nanosheets have been inspected by Williamson-Hall analysis. The quantum size effect outcomes in spectacular variation in the optical and vibrational appearances of nanostructured materials likened to their bulk counterparts. Nanosheets like optical image were observed in the microscopy studies. Functional tests of SnO2 nanosheets include photocatalytic effect in the degradation of methylene blue (MB). The result revealed that SnO2 nanosheets degraded 84% of MB under UV light illumination. Dielectric studies such as dielectric constant, loss and ac conductivity were determined.
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水热合成SnO2纳米片的合成、表征及高效光催化活性研究
对水热法制备SnO2纳米片进行了系统的研究。以二氢氯化锡和氢氧化钠为前驱体,碱性水混合,合成了四方相SnO2。采用XRD、HRSEM、EDAX、FTIR和紫外可见光谱对合成的样品进行了表征。采用Williamson-Hall分析方法对SnO2纳米片的纳米晶尺寸和应变进行了表征。量子尺寸效应导致纳米结构材料的光学和振动外观发生了惊人的变化,与它们的块状对应物相比。在显微镜下观察到纳米片状光学图像。SnO2纳米片的功能测试包括光催化降解亚甲基蓝(MB)的效果。结果表明,在紫外光照射下,SnO2纳米片降解了84%的MB。电介质研究,如介电常数,损耗和交流电导率测定。
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