Nanocomposite for Space Charge Suppression in HVDC Cable Accessory

B. Du, Jin Li, Zhuoran Yang
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Abstract

HVDC cable accessories made of ethylene-vinyl acetate copolymer (EVA) by incorporation of specific fillers have to face the problem of space charge accumulation. The effects of doping contents on the space charge behaviors of EVA/ZnO composite are not completely clear. EVA composites are prepared with the fraction of 0, 1, 5 and 10 wt%, respectively, with which 5 wt% nano-sized plus 5 wt% micro-sized ZnO-doped samples are chosen for comparison. Obtained results show that the particles in EVA composite are in homodisperse. The permittivity is increased by ZnO doping and the dissipation factor of EVA composites with 1 and 5 wt% nanoparticles is lower at the lower frequencies. The homocharge injection occurs in cathode instead of anode when ZnO nanoparticles are introduced and 5 wt% nanoparticle doping performs well in suppressing space charge injection. The electric field in the 5 wt% nanoparticle-doped EVA distributes more uniformly under the high electric stress than that of others. During the depolarization procedure, the total remnant charges of 10 wt% doped samples are the least in the final. The above results are well explained by the DC conduction, apparent mobility and trap distribution characteristics.
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高压直流电缆附件中空间电荷抑制的纳米复合材料
由乙烯-醋酸乙烯共聚物(EVA)掺入特定填料制成的高压直流电缆附件,面临空间电荷积累的问题。掺杂量对EVA/ZnO复合材料空间电荷行为的影响尚不完全清楚。分别制备了分数为0、1、5、10 wt%的EVA复合材料,选择5 wt%纳米级和5 wt%微级zno掺杂样品进行比较。结果表明,EVA复合材料中的颗粒呈均匀分散状态。ZnO的掺杂提高了EVA复合材料的介电常数,并且在较低的频率下,含有1 wt%和5 wt%纳米颗粒的EVA复合材料的耗散系数较低。当ZnO纳米粒子引入时,在正极发生了同电荷注入,而在正极则发生了同电荷注入,并且5 wt%的纳米粒子掺杂抑制了空间电荷注入。在高电应力下,掺5wt %纳米粒子的EVA的电场分布比其他EVA的电场分布更均匀。在退极化过程中,10%掺杂样品的总残余电荷在最后是最少的。上述结果很好地解释了直流传导、表观迁移率和陷阱分布特性。
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