THE CHANGES IN THE SURFACE OF FLAT PRESSED WOOD-PLASTIC COMPOSITES EXPOSED TO ARTIFICIAL WEATHERING

Sefa Durmaz, Özlem Özgenç
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Abstract

In this study, the wood flour content's effect on the weathering performance of flat pressed WPC was investigated. The high density polyethylene was reinforced with four different wood flour content (10%, 30%, 50%, 70%). The weathering performance of WPC was determinedby the 400 h of artificial weathering test. According to the results, the color change is inevitable aslong as the wood flour is used as filler. Surprisingly, the highest color change was obtained from WPC containing 30% WF, contrary to 70% of wood flour. Similarly, the whiteness of thesurface of WPC increased with exposure time. The photooxidation resulted in the chain scission and shorter molecules, which were observed by ATR-FTIR analysis. The changes in the intensity of characteristic polymer (2914 cm-1and 2846 cm-1) and wood peaks (1510 cm-1and 1027 cm-1) exhibited the photodegradation on WPCs' surface, which resulted in color change. Moreover, the light microscopy investigation showed surface degradation. Theextensive weathering conditions causedsurface cracks and surface roughness. The visual appearance of WPCs also demonstrated how to change the surface character of WPC during the400 h of artificial weathering. In conclusion, the increase inthe wood content increased theintensity of degradation.
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平面压制木塑复合材料在人工风化作用下的表面变化
研究了木粉含量对平压木塑耐候性的影响。采用四种不同木粉含量(10%、30%、50%、70%)对高密度聚乙烯进行增强。通过400 h的人工风化试验,测定了木塑复合材料的风化性能。结果表明,只要使用木粉作为填料,颜色变化是不可避免的。令人惊讶的是,与70%木粉相反,含有30% WF的木胶的颜色变化最大。同样,随着曝光时间的增加,木塑表面的白度也增加。通过ATR-FTIR分析发现,光氧化导致分子链断裂,分子变短。特征聚合物强度(2914 cm-1和2846 cm-1)和木峰强度(1510 cm-1和1027 cm-1)的变化表明WPCs表面发生了光降解,导致颜色变化。此外,光镜检查显示表面降解。广泛的风化条件造成了表面裂缝和表面粗糙度。复合材料的视觉外观也展示了复合材料在400 h的人工风化过程中如何改变其表面特性。综上所述,木材含量的增加增加了降解的强度。
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