Breakdown of polymer: Tree initiation and growth

R. Patsch
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引用次数: 10

Abstract

Encouraged by economic considerations, great efforts have been undertaken in the last decade to improve solid-state hv cable insulations. A multitude of additives was examined with the aim of upgrading the electric strength of polyethylene commonly used for hv cables. Hundreds of laboratory tests, mainly based on a method proposed by Kitchin and Pratt,1 were carried out; but most additives which increased tree inception voltage were not successful in experiments with full size or prototype cables. This is often due to the fact that in a remote ground electrode arrangement or flat brick-shaped specimen (often preferred to ascertain tree inception by optical observation) the correlation between test voltage and field strength at the needle tip may be influenced by the surface conductivity of the polymer. Additives increasing the surface conductivity of the examined polymer over a critical value depending on the geometry of the specimen and the properties of the embedding fluid may make the electric field between needle tip and the opposite electrode more uniform. Hence the field enhancement at the needle tip is decreased and the critical field strength leading to tree initiation can only be attained at higher test voltages.2
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聚合物的分解:树的形成和生长
在经济考虑的鼓励下,在过去的十年里,人们已经做出了巨大的努力来改善固态高压电缆的绝缘。为了提高高压电缆中常用的聚乙烯的电强度,研究了多种添加剂。进行了数百次实验室测试,主要基于Kitchin和Pratt提出的方法1;但大多数增加起始电压的添加剂在全尺寸或原型电缆的实验中都不成功。这通常是由于这样一个事实,即在遥远的接地电极布置或平坦的砖形试样中(通常倾向于通过光学观察确定树的起始),针尖处的测试电压和场强之间的相关性可能受到聚合物表面电导率的影响。根据试样的几何形状和包埋流体的性质,将所测聚合物的表面电导率提高到临界值以上的添加剂可使针尖和对电极之间的电场更加均匀。因此,针尖处的电场增强减弱,只有在更高的测试电压下才能达到导致树形起始的临界场强
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