Electrical and optical properties of liquid conducting polymer

K. Yoshino, K. Sawada, S. Morita, Y. Nishioka, M. Fukuda, T. Kawai, Y. Ohmori
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引用次数: 1

Abstract

Conducting polymers with substituted long side chain such as poly(3-alkylthiophene), poly(3-alkyl-selenophene), poly(3alkylfuran), poly(9-alkylfluorene), and poly(9,9-dialkylfluorene) are shown to melt at relatively low temperature. Electrical conductivity and photoluminescence exhibit an anomalous dependence on molecular structures at the melting point. A marked polarity effect of photoconduction has been observed. These results are discussed in terms of unique band schemes of the conducting polymers in the premelting region and in the liquid state.<>
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液体导电聚合物的电学和光学性质
具有取代长侧链的导电聚合物,如聚(3-烷基-噻吩)、聚(3-烷基-硒基)、聚(3-烷基呋喃)、聚(9-烷基芴)和聚(9,9-二烷基芴)在较低温度下熔化。电导率和光致发光表现出异常依赖于熔点处的分子结构。观察到光导的显著极性效应。从预熔区和液相中导电聚合物的独特能带方案的角度对这些结果进行了讨论。
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