Degradation of AMARANTH with TiO2 Synthesised by Sol-Gel Process

Cristina Moncada-Sánchez, M. Salazar-Hernández, J. C. Baltazar-Vera, Martín Caudillo-González
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Abstract

The photo-degradation of persistent contaminants in aqueous systems such as drugs, pesticides or dyes has been proposed as an alternative for the remediation of aqueous systems. TiO2 is one of the main photocatalysts that have been used for these purposes, it has two phases with photocatalytic properties, anatase and rutile, the latter being the one with the lowest conduction band 3.0 eV. The present work shows the synthesis of TiO2 by sol gel process, observing that the rutile phase is favored with heat treatment at temperatures above 600ºC, the comparative study of the degradation kinetics of AMARANTH with synthesized TiO2 and commercial TiO2 was evaluated, observing a rate constant of 1.38 and 0.345 Lmol-1min-1 for commercial and synthetic TiO2, respectively.
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溶胶-凝胶法制备TiO2降解紫红花
光降解水系统中的持久性污染物,如药物、农药或染料,已被提出作为水系统修复的替代方法。TiO2是目前用于这些目的的主要光催化剂之一,它有锐钛矿和金红石两种具有光催化性能的相,金红石的导带最低,为3.0 eV。本文采用溶胶-凝胶法合成TiO2,观察到金红石相在600℃以上的温度下热处理更有利于金红石相,并对AMARANTH对合成TiO2和商用TiO2的降解动力学进行了比较研究,发现商用TiO2和合成TiO2的降解速率常数分别为1.38和0.345 Lmol-1min-1。
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