Spectroscopic properties of Nd3+/Yb3+ co-doped in lithium aluminum silicate glass for 1.0 μm fiber laser

Kexuan Han, F. Yu, Yanyan Guo
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引用次数: 5

Abstract

The Nd3+, Yb3+ singly doped and Nd3+ /Yb3+ co-doped lithium aluminum silicate glasses are fabricated by using a conventional melt quenching technique in air atmosphere, with the molar composition of (60-a-b)SiO2-3Al2O3-20Li2O-12MgO-5CaO-aNd2O3-bYb2O3 (with a=0, 0.25, 0.5, 1 and b=0,2). The Spectroscopic properties of 1.0 μm emission and Luminescence lifetime in Nd3+ /Yb3+ co-doped lithium aluminum silicate glasses are investigated under 808 nm excitation. The Judd–Ofelt theory is used to study the spectroscopic properties of Nd3+ . Meanwhile, the emission cross-section of Yb3+ are obtained by using the reciprocity method. A broad emission band from 950 to 1,100 nm is detected when the Nd3+ /Yb3+ co-doped in lithium aluminum silicate glasses excited by 808 nm LD. The energy transfer process from Nd3+ →Yb3+ co-doped in lithium aluminum silicate glasses is described in this paper.
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1.0 μm光纤激光器中Nd3+/Yb3+共掺硅酸铝锂玻璃的光谱特性
采用常规空气熔体淬火技术制备了Nd3+、Yb3+单掺杂和Nd3+ /Yb3+共掺杂的硅铝锂玻璃,其摩尔组成为(60-a-b) sio2 - 3al2o3 - 20li2o - 12mgo - 5cao -和2o3 - byb2o3 (a= 0,0.25, 0.5, 1, b=0,2)。研究了Nd3+ /Yb3+共掺硅酸锂铝玻璃在808 nm激发下的1.0 μm发射光谱特性和发光寿命。利用Judd-Ofelt理论研究了Nd3+的光谱性质。同时,利用互易法得到了Yb3+的发射截面。在808 nm的LD激发下,Nd3+ /Yb3+共掺杂在硅酸铝锂玻璃中有950 ~ 1100 nm的宽发射带,描述了Nd3+→Yb3+共掺杂在硅酸铝锂玻璃中的能量传递过程。
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