The new approach to determination of the combined isotopic composition of methane for its genetic characterization

A. Makas, A. Kudryavtsev, M. Troshkov
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Abstract

A new approach to mass-spectrometric determination of the combined isotopic composition of methane has been put forward. The approach is based on the preliminary on-line conversion of methane to methanol in corona discharge and selective chemical ionization. The approach provides means to lower requirements for equipment, consumables, and operation conditions and offers a challenge to develop a new field method.
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甲烷组合同位素组成测定的新方法及其成因表征
提出了一种用质谱法测定甲烷组合同位素组成的新方法。该方法是基于电晕放电和选择性化学电离的甲烷在线转化为甲醇的初步方法。该方法为降低对设备、耗材和作业条件的要求提供了手段,并对开发新的现场方法提出了挑战。
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