Use of nanotubular TiO2 films for the photo-degradation of emerging contaminants (drugs) in water

Kendra Martínez-Flores, S. Ortíz-Gómez, P. Mijaylova-Nacheva, C. Cuevas-Arteaga
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Abstract

 Provide in a single paragraph of 300 words maximum an overview of the work, including background, methodology, main results, and conclusions.  One of the biggest problems of the 21st century is perhaps the need to provide water for the growing world population. Faced with this global problem around water, pollution is a factor of great importance, since the pollutants generated by industrial and domestic activity can be accumulated and transported by both surface and underground waters, deteriorating their quality. Therefore, it is necessary to study the behavior of these pollutants in water and propose treatment techniques that can eliminate them. Regarding water treatment techniques, it has been shown that heterogeneous photocatalysis with TiO2 is a clearly effective and environmentally an advantageous alternative for the removal of organic substances in aqueous media. In photocatalysis degradation processes, the analysis of the influence of the surface phenomena on the degradation reactions is of special interest. In the present work, the preparation of TiO2 self-ordered nanotubular films was carried out by means of the electrochemical anodization technique using the electrolyte: 50% Vol. Glycerol + 50% Vol. H2O + NH4F [0.27M), to be utilized in a Photocatalytic Reactor (FR) for the photodegradation of Metoprolol in order to evaluate the efficiency of the heterogeneous photocatalytic as an Advanced Oxidation Processes (AOP) through the photodegradation of the emerging pollutant under study and determine the efficiency of the photodegradation through the technique of gas chromatography coupled to mass spectrometry (GC-MS).
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纳米管TiO2薄膜用于水中新出现的污染物(药物)的光降解
在不超过300字的一段话内概述工作,包括背景、方法、主要结果和结论。21世纪最大的问题之一可能是需要为不断增长的世界人口提供水。面对这个围绕水的全球性问题,污染是一个非常重要的因素,因为工业和家庭活动产生的污染物可以通过地表水和地下水积累和运输,从而使其质量恶化。因此,有必要研究这些污染物在水中的行为,并提出可以消除它们的处理技术。在水处理技术方面,研究表明,TiO2的多相光催化是一种明显有效且环境有利的水介质中有机物去除方法。在光催化降解过程中,分析表面现象对降解反应的影响具有特殊的意义。在本工作中,利用电解液,采用电化学阳极氧化技术制备TiO2自有序纳米管薄膜:50% Vol. Glycerol + 50% Vol. H2O + NH4F [0.27M],在光催化反应器(FR)中进行美托洛尔的光降解,以评价多相光催化作为一种高级氧化工艺(AOP)通过光降解所研究的新兴污染物的效率,并通过气相色谱-质谱联用(GC-MS)技术确定光降解效率。
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