Spectral Holeburning in Tetraphenylporphyrin Doped Polymethylcellulose

K. Dou, Jisen Zhang, M. Tian, Jiahua Zhang, C. Jin, Jialong Zhao, Shi-hua Huang, Jiaqi Yu
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Abstract

In our previous works, some holeburning results in organic materials with charge transfer were given. We achieved the photon-gated holeburning in a system containing the electron acceptor (p-hydroxybenzaldhyde (PHBA)) and the electron donor (Zn-tetraphenylbenzoporphyrin (Zn-TPBP) doped in a matrix (poly-methylmethacrylate (PMMA) ) [1-3]. In this paper, we will report the single photon holeburning at 25K in p- tetraphenylporphyrin (TPP) embedded in the matrix of polymethylcellulose. The mechanisms of holeburning and holefilling are discussed.
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四苯基卟啉掺杂聚甲基纤维素的光谱烧孔
在我们以前的工作中,给出了一些有电荷转移的有机材料的烧孔结果。我们在一个包含电子受体(对羟基苯甲醛(PHBA))和电子供体(掺杂在基体(聚甲基丙烯酸甲酯(PMMA))中的zn -四苯基苯并卟啉(Zn-TPBP))的体系中实现了光子门控烧穴[1-3]。在本文中,我们将报道嵌入在聚甲基纤维素基质中的对四苯基卟啉(TPP)在25K下的单光子烧孔。讨论了烧孔和填孔的机理。
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