Non-destructive prediction of soluble solids content in citrus using visible near-infrared spectroscopy

Yuan Qin, Shaokang Huang, Z. Huang, Xiaoxiao Jiang
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Abstract

The soluble solids content (SSC) of fruits is an important parameter that influences its internal quality. Visible near-infrared (Vis-NIR) spectroscopy is a effective means to detect the internal quality of fruits and vegetables. Measuring samples by instruments generates noise due to environmental factors and machine vibrations, which affects the accuracy of predictions. In this paper, we use standard normalized variables (SNV) and multiplicative scattering correction (MSC) to preprocess the spectral wavelengths, which can effectively reduce the effect of noise. In addition, spectral data contain many redundant variables and useless information, leading to poor prediction of the model. In order to solve this problem, this paper propose a wavelength selection method based on a hybrid strategy of Genetic Algorithm (GA) and Competitive Adaptive Reweighted Sampling (CARS) to screen the effective variables. And the final model is created by partial least squares (PLSR). The GA-CARS model with 84 selected variables has better predictive performance compared to the origin spectrum. In the experiments, samples are obtained from fresh citrus grown in farms around Guilin, and the spectra of citrus are detected in the range of 590 nm-940 nm with a Vis-NIR spectrometer. The experimental results showed that the performance of the prediction model is improved after wavelength screening (RMSEP=0.1581, R2=0.9245). Compared with the traditional algorithm, GA-CARS is an excellent method for screening variables, and the screened wavelengths combined with the model established by PLSR can be a rapid means to detect the SSC of citrus.
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用可见近红外光谱无损预测柑橘中可溶性固形物含量
可溶性固形物含量(SSC)是影响果实内在品质的重要参数。可见近红外光谱(Vis-NIR)是检测果蔬内在品质的有效手段。由于环境因素和机器振动,仪器测量样品会产生噪声,影响预测的准确性。本文采用标准归一化变量(SNV)和乘法散射校正(MSC)对光谱波长进行预处理,可以有效降低噪声的影响。此外,光谱数据中含有大量冗余变量和无用信息,导致模型的预测效果较差。为了解决这一问题,本文提出了一种基于遗传算法(GA)和竞争自适应重加权采样(CARS)混合策略的波长选择方法来筛选有效变量。最后利用偏最小二乘法(PLSR)建立模型。与原始谱相比,具有84个选择变量的GA-CARS模型具有更好的预测性能。实验以桂林市周边农场的新鲜柑橘为样品,利用Vis-NIR光谱仪在590 nm-940 nm范围内检测柑橘的光谱。实验结果表明,经过波长筛选后,预测模型的性能得到了提高(RMSEP=0.1581, R2=0.9245)。与传统算法相比,GA-CARS是一种很好的筛选变量的方法,筛选出的波长与PLSR建立的模型相结合,可以快速检测柑橘的SSC。
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