Synthesis and Characterization of Strontium Doped Barium Titanate Ceramics

A. Elbasset, F. Abdi, T. Lamcharfi, S. Sayouri, M. Aillerie
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引用次数: 3

Abstract

In order to investigate effect doping with strontium on structural and dielectric properties of BaTiO3, a series of B1-xSrxTiO3 (BSxT) ceramic powders (0, 0.05, 0.1, 0.15, 0.2, 0.3, 0.4 and 0.5) were prepared by the sol gel method. The phase formation and crystal structure of BaTiO3 were checked by X-ray diffraction analysis and Raman spectroscopy. It was observed that the quadratic structure of the pure sample transforms to pseudo cubic under Sr substitution. The morphology and microstructure of the samples were examined by scanning electron microscopy (SEM); a quiet regular morphology in shape was observed with an average grain size of 2 m in accordance with that reported in the literature. The dielectric investigations show that BST is a classical ferroelectric material and that the temperature of the maximum of the permittivity, Tm, decreases with Sr content.
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掺锶钛酸钡陶瓷的合成与表征
为了研究锶掺杂对BaTiO3结构和介电性能的影响,采用溶胶-凝胶法制备了一系列B1-xSrxTiO3 (BSxT)陶瓷粉体(0、0.05、0.1、0.15、0.2、0.3、0.4和0.5)。利用x射线衍射分析和拉曼光谱对BaTiO3的相形成和晶体结构进行了表征。结果表明,在Sr取代作用下,纯样品的二次元结构转变为伪三次元结构。采用扫描电子显微镜(SEM)对样品的形貌和显微结构进行了观察;在形状上观察到安静的规则形态,平均晶粒尺寸为2m,与文献报道一致。电介质研究表明,BST是一种经典的铁电材料,其介电常数最大值Tm随Sr含量的增加而降低。
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