RESEARCH OF THE PROPERTIES OF ZINC OXIDE NANOSTRUCTURES OBTAINED BY PULSED ELECTROCHEMICAL DEPOSITION

M. N. Ilyina, A. N. Voropay, I. Nemchenok
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Abstract

The properties of zinc oxide nanostructures allow it to be used in various fields of science and technology. The increased interest in this compound is caused by a rare combination of optical and electrophysical properties. The films of this compound have good piezoelectric and electroluminescent properties, due to which zinc oxide can be used as functional layers in surface acoustic waves, elements of nonlinear optics. This allows the oxide to pass visible radiation. In this paper, we study the influence of the conditions for obtaining a coating by pulsed electrochemical deposition on the forbidden zones and the power of a coating based on zinc oxide. It was shown that the temperature and duty cycle of pulses are of great importance in the formation of the coating, which is explained by the kinetics of the electrochemical reaction. The Urbach energy increases with a decrease in crystalline size and increased by almost 3 times, compared with a coarse-grained sample.
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脉冲电化学沉积法制备氧化锌纳米结构的性能研究
氧化锌纳米结构的特性使其可以应用于各种科学技术领域。人们对这种化合物越来越感兴趣是由于其罕见的光学和电物理性质的结合。该化合物的薄膜具有良好的压电和电致发光性能,因此氧化锌可以用作非线性光学元件表面声波的功能层。这使得氧化物可以通过可见辐射。本文研究了脉冲电化学沉积法制备镀层的条件对氧化锌镀层的禁化带和功率的影响。结果表明,脉冲的温度和占空比对镀层的形成有重要影响,这可以用电化学反应动力学来解释。乌尔巴赫能量随着晶粒尺寸的减小而增加,与粗粒度样品相比增加了近3倍。
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