Preparation of mesostructure amorphous aluminum-methionine and its potency as adsorbent

Ery Susiany Retnoningtyas, Y. Ju, Cheng-Kang Lee, S. Ismadji, C. Gunarto, A. Ayucitra, Artik Elisa Angkawijaya
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Abstract

An amorphous metal-amino acid contains metal based on Aluminium and Methionine as a ligand, was synthesized. The fabricated amorphous Al-Methionine (a-AM) is done in water solvent under moderate thermal conditions. The advantages of using bio ligands, one of which is amino acid, can be used to biologically compatible material. The synthesis was optimized changing chemical (metal and ligand molar ratio) and process (temperature, time) parameters. The a-AM characterization was carried out by XRD, FTIR spectroscopy, FESEM, also gas sorption measurement (BET). From the N2 adsorption/desorption isotherm, the a-AM is classified as a type IV and has a mesoporous structure. The produced a-AM has a SBET area 287 m2 g−1, pore size 0.996 cm-3 g−1 and mean pore diameter 13.85 nm. After demonstrated in the dye adsorption, this material has potency as an adsorbent.
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介结构无定形铝-蛋氨酸的制备及其吸附剂性能
合成了一种以铝为基材,以蛋氨酸为配体的无定形金属氨基酸。在中等热条件下,在水溶剂中制备了非晶al -蛋氨酸(a-AM)。利用生物配体的优点,其中之一是氨基酸,可以用于生物相容性材料。通过改变化学参数(金属与配体的摩尔比)和工艺参数(温度、时间)对合成工艺进行优化。采用XRD、FTIR、FESEM、BET等方法对a-AM进行表征。从N2吸附/解吸等温线来看,a- am为ⅳ型,具有介孔结构。制备的a- am的SBET面积为287 m2 g−1,孔径为0.996 cm-3 g−1,平均孔径为13.85 nm。经染料吸附实验证明,该材料具有吸附剂的作用。
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