Nanostructured MnO2 for phenolic compounds degradation and monitoring

R. Di Chio, F. Arena, S. Leonardi, G. Neri, N. Donato
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引用次数: 1

Abstract

In this paper, the oxidative degradation of phenolic compounds and their electrochemical monitoring by using nanostructured MnO2 is reported. MnO2 was synthesized by the redox-precipitation method and used as a catalyst for the wet air oxidation (CWAO) of phenol as a model compound under mild reaction conditions (T, 423 K; P, 1.4 MPa).The synthesized MnO2 nanoparticles display also good electrochemical properties and have been applied here to fabricate modified screen printed carbon electrode (SPCE) for rapid detection of phenolic compounds (phenol, hydroquinone and cathecol) in waste water.The reported results demonstrated the great potential of nanostructured MnO2 in the field of marine ambient pollution reduction and monitoring.
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纳米二氧化锰对酚类化合物的降解及监测
本文报道了纳米二氧化锰对酚类化合物的氧化降解及其电化学监测。采用氧化还原沉淀法合成MnO2,并在温和反应条件下(T, 423 K;P, 1.4 MPa)。合成的二氧化锰纳米颗粒也显示出良好的电化学性能,并应用于制备改性丝网印刷碳电极(SPCE),用于废水中酚类化合物(苯酚、对苯二酚和苯酚)的快速检测。研究结果表明,纳米二氧化锰在海洋环境污染减少和监测领域具有巨大的潜力。
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