Utilizing Hole-Type Sensitizer Tris (Phenylpyrazole) Iridium (Ir(ppz)3) to Realize Efficient Red Organic Light-Emitting Devices

Xiaokang Li, Zhanguo Li, Guojun Liu
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Abstract

We design and fabricate highly efficient red organic electroluminescent (EL) devices by utilizing iridium(III) bis(2-phenylquinoly-N,C2’)dipiva1oy1methane $(\mathrm{P}\mathrm{Q}_{2}\mathrm{I}\mathrm{r}(\mathrm{d}\mathrm{p}\mathrm{m}))$ and tris(phenylpyrazole) iridium $(\mathrm{I}\mathrm{r}(\mathrm{p}\mathrm{p}\mathrm{z})_{3})$ as emitter and hole-type sensitizer, respectively. Experimental results demonstrated that sensitizer molecules within hole-dominant EML function as hole trappers, thus delaying the transport of holes. Finally, the optimized co-doped device obtained the external quantum efficiency, maximum brightness and current efficiency up to 18.9%, 87370 cd/m2 and 51.09 cd/A, respectively.
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利用孔型敏化剂Tris(苯吡唑)铱(Ir(ppz)3)实现高效红色有机发光器件
我们利用铱(III)双(2-苯基喹啉- n,C2′)双pipiva1oy1methane $(\ mathm {P}\ mathm {Q}_{2}\ mathm {I}\ mathm {r}(\ mathm {d}\ mathm {P}\ mathm {m}))$和三(苯基吡唑)铱$(\ mathm {I}\ mathm {r}(\ mathm {P}\ mathm {z})_{3})$分别作为发射极和空穴型敏化剂设计和制造了高效的红色有机电致发光器件。实验结果表明,敏化剂分子在空穴优势EML中起着空穴诱捕剂的作用,从而延缓了空穴的传输。最后,优化后的共掺杂器件的外量子效率、最大亮度和电流效率分别达到18.9%,87370 cd/m2和51.09 cd/A。
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