MODERN ANALYTICAL TECHNOLOGIES IN EARTH SCIENCES

Gao Yu-shu
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引用次数: 1

Abstract

The idea of modern geoanalysis is briefly describe d . Modern technologies and methods of geoanalysis are introduced and reviewed from six aspects: bulk analysis; micro-(in situ)analysis and element distribution analysis; structure, image and valence state analysis; organic and speciation analysis; age-dating and stable-isotope methods; and field(in situ) analysis techniques. The main content of each part is as follows: The idea of modern geoanalysis is shown by describing its history,development ,formation of the idea and development trends in the future. Currently,the most important Bulk Analysis techniques are X-Ray Fluorescence Spectrometry(XRF), Inductively Coupled Plasma Atomic Emission Spectrometry(ICP-AES), ICP Mass Spectrometry(ICP-MS), Instrument Neutron Activation Analysis (INAA)and Total Reflection XRF(TRXRF). Microanalysis(in situ)and Element Distribution Analysis(element map) techniques include:①Electron micro-beam techniques: Electron Microprobe Analysis(EMPA), Scanning Electron Microscopy(SEM), Analytical Electron Microscopy (AEM)and Transmitted Electron Microscopy (TEM);②X-ray and high-energy ion-beam techniques: Synchrotron Radiation X-ray Microprobe(SRXRM)and Scanning Nuclear Microprobe(SNM);③Laser and low energy ion-beam techniques: Laser Ablation ICP-MS(LA-ICP-MS) and Secondary Ion Mass Spectrometry(SIMS). Structure,image, and valence state analysis techniques involve: X-Ray Diffraction (XRD),various Electron Microscopy(EMPA, SEM, AEM and TEM)and some surface analysis techniques: Electron Spectroscopy for Chemical Analysis(ESCA),Auger Electron Spectroscopy(AES), Extended X-ray Absorption Fine Structure(EXAFS), X -ray Absorption Near Edge Structure(XANES) and Scanning Tunneling Microscope(STM )or Atomic Force Microscope(AFM). As a result of demands of energy-minerals and environment-geoscience research,the organic component and speciation analysis has been other important field in modern geoanalysis. Main techniques are Gas Chromatography(GC),Mass Spectrometry(MS),High Performance Liquid Chromatography(HPLC),Capillary Electrophoresis(CE), Laser Laman Spectroscopy(LLS),Fourier Infrared Spectrometry(FIRS), chemical sensor and their combined techniques.Dating and stable isotope analysis techniques include: the conventional TIMS,NIMS and new micro-dating techniques: SIMS,SHRIMP,LA-ICP-MS,AMS and Laser probe Ar/Ar dating.The field and in situ analysis techniques include: the geochemical detect of extraterrestrial materials, the analysis techniques on board and under water for marine mineral resources, the field analysis for general survey, mining, drill core and well logging.
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现代地球科学分析技术
简述了现代地理分析的思想。从六个方面介绍和评述了现代地质分析技术和方法:本体分析;微量(原位)分析和元素分布分析;结构、图像和价态分析;有机物和物种分析;年龄测年和稳定同位素法;现场(原位)分析技术。各部分的主要内容如下:通过描述现代地理分析的历史、发展、思想的形成和未来的发展趋势来展示现代地理分析的思想。目前,最重要的体分析技术有x射线荧光光谱法(XRF)、电感耦合等离子体原子发射光谱法(ICP- aes)、ICP质谱法(ICP- ms)、仪器中子活化分析(INAA)和全反射XRF(TRXRF)。微量分析(原位)和元素分布分析(元素图)技术包括:①电子微束技术:电子微探针分析(EMPA)、扫描电镜(SEM)、分析电镜(AEM)和透射电镜(TEM);②x射线和高能离子束技术:同步辐射x射线微探针(SRXRM)和扫描核微探针(SNM);③激光和低能离子束技术;激光烧蚀ICP-MS(LA-ICP-MS)和次级离子质谱(SIMS)。结构、图像和价态分析技术包括:X射线衍射(XRD)、各种电子显微镜(EMPA、SEM、AEM和TEM)和一些表面分析技术:化学分析电子能谱(ESCA)、埃格电子能谱(AES)、扩展X射线吸收精细结构(EXAFS)、X射线吸收近边结构(XANES)和扫描隧道显微镜(STM)或原子力显微镜(AFM)。由于能源矿产和环境地球科学研究的需要,有机成分和物种形成分析已成为现代地球分析的另一个重要领域。主要技术有气相色谱(GC)、质谱(MS)、高效液相色谱(HPLC)、毛细管电泳(CE)、激光拉曼光谱(LLS)、傅立叶红外光谱(FIRS)、化学传感器及其组合技术。测年和稳定同位素分析技术包括:传统的TIMS、NIMS和新的微测年技术:SIMS、SHRIMP、LA-ICP-MS、AMS和激光探针Ar/Ar测年。现场和现场分析技术包括:地外物质地球化学探测、海洋矿产资源的船上和水下分析技术、普查、采矿、岩心和测井现场分析。
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