Effect of codoping of Zn2+ ion on the upconversion of Er3+-Yb3+ codoped Y2O3 phosphor

Riya Dey, A. Pandey, V. K. Rai
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引用次数: 1

Abstract

The frequency upconversion emission from Er3+-Yb3+ codoped Y2O3 phosphor synthesized by low temperature, urea assisted combustion technique has been studied upon excitation at 980 nm diode laser. The effect of incorporation of Zn2+ ion on upconversion (UC) emission bands around 409 nm, 523 nm, 551 nm, 661 nm arises due to the transitions 2H9/24I15/2, 2H11/24I15/2, 4S3/24I15/2 and 4F9/24I15/2 of Er3+ ions have been investigated. The basic mechanism involved in UC process and reason of intensity enhancement on Zn2+ codoping have been explained by energy level structure and decay time analyses. The present study indicates that the developed phosphors may be of significant interest for use in photonic applications.
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Zn2+离子共掺杂对Er3+-Yb3+共掺杂Y2O3荧光粉上转换的影响
研究了低温尿素辅助燃烧技术合成的Er3+-Yb3+共掺Y2O3荧光粉在980 nm二极管激光激发下的频率上转换发射。研究了Zn2+离子掺入对Er3+离子由2H9/2→4I15/2、2H11/2→4I15/2、4S3/2→4I15/2和4F9/2→4I15/2产生的409 nm、523 nm、551 nm、661 nm左右的上转换(UC)发射带的影响。通过能级结构和衰减时间分析,解释了UC过程的基本机理和Zn2+共掺杂强度增强的原因。目前的研究表明,所开发的荧光粉在光子应用方面可能具有重要的意义。
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