Growth and photorefractive properties of Zr:Cu:Fe:LiNbO3 crystals with various Li/Nb ratios

Xiaoling Zhang, Xin Zhang, J. Tong, Jie Gao, Lijie Jin, Zhaopeng Xu
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Abstract

A series of Zr(1 mol%):Cu(0.1 mol%):Fe(0.03wt%)LiNbO3 single crystals with various Li/Nb ratios having compositions varying between 48.6 and 58 mol% Li2O in the melt were grown by the Czochralski method in the air. The OH− transmittance spectra was investigated to characterize the structure defects of these crystals. The OH− absorption peaks shift to longer wavelength as the [Li]/[Nb] ratio increases and an obvious absorption peak at 3468 cm-1 was observed at the Li/Nb ratio of 1.05. The photorefractive properties of the crystals were experimentally studied using the two-wave coupling method. The results show that as the [Li]/[Nb] ratio increases, the holographic response time and the diffraction efficiency increase under the Li/Nb ratio of 1.2.
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不同Li/Nb比Zr:Cu:Fe:LiNbO3晶体的生长和光折变特性
用Czochralski法在空气中生长出一系列具有不同Li/Nb比的Zr(1mol %):Cu(0.1 mol%):Fe(0.03wt%)LiNbO3单晶,其Li2O组成在48.6 ~ 58 mol%之间。通过OH -透射光谱表征了这些晶体的结构缺陷。随着[Li]/[Nb]比的增加,OH -吸收峰向更长的波长移动,在Li/Nb比为1.05时,在3468 cm-1处有明显的吸收峰。采用双波耦合的方法对晶体的光折变特性进行了实验研究。结果表明:当Li/Nb比为1.2时,随着[Li]/[Nb]比的增加,全息响应时间和衍射效率增加;
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