Electrochemical behavior of dibutyl methyl ester p-tert-butyl calix [4] arene

Lilia Tabti, M. R. Khelladi
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Abstract

The electrochemical behavior of dibutyl methyl ester p-tert-butylcalix [4] arene compound 1 was studied by cyclic voltammetry. At25°C and scan rate of 20 mVs−1. The anodic peak is affected by scanrate, concentration and temperature is a totally irreversible process.The result shows that there is an irreversible electrochemicaloxidative wave when the potential is more 1.3 V versus Ag/AgCl inan acetonitrile.    
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对叔丁基杯[4]芳烃二丁甲酯的电化学行为
采用循环伏安法研究了对叔丁基杯[4]芳烃化合物1的电化学行为。在25°C下,扫描速率为20 mv−1。阳极峰受钪、浓度和温度的影响是一个完全不可逆的过程。结果表明,当电位大于1.3 V时,Ag/AgCl在乙腈中产生不可逆的电化学氧化波。
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