Evaluation the Effect of Trichloroethylene on the Metal-Ceramic Bonding

Nurten Baysal, B. Erol, S. Ayyıldız
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Abstract

The aim of the study is to evaluate the effect of trichloroethylene (TCE) on the metal-ceramic bond of ‎additively manufactured and casting Co-Cr alloys. For this purpose, 84 disc-shaped (r=12 mm, h=1 mm) ‎specimens were prepared for two experimental groups (n=42) with different fabrication techniques; casting ‎and additively manufactured with Co-Cr. Before ceramic application, the disc specimens divided into two ‎subgroups (n=21): Casting and cleaned with TCE (CT), casting and not cleaned with TCE (C), additively ‎manufactured and cleaned with TCE (AT), additively manufactured and not cleaned with TCE (A). Ceramic ‎‎(h=4 mm, r=6 mm) was applied to the disc specimens (n=20) and their shear bond strength (SBS) was ‎measured. The surface morphology of disc (n=1; for each subgroup) specimens before and after TCE ‎application was analyzed with a scanning electron microscope (SEM). Results were statistically analyzed with ‎‎1-way ANOVA and the Bonferroni multiple comparisons tests (α=0.05). Significant differences were found in ‎SBS of the CT, C, AT, and A groups. CT group (21.74±1.66 MPa) showed a significantly higher SBS value ‎than the C (18.65±2.11 MPa), AT (19.07±1.75 MPa) and A (18.52±1.94 MPa) groups (p<0.001). In ‎conclusion the application of the TCE increased the metal-ceramic bond of casting Co-Cr alloy. Although the ‎results were not statistically significant the TCE also increased the bond of additively manufactured Co-Cr ‎alloy.
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三氯乙烯对金属-陶瓷键合效果的评价
研究了三氯乙烯(TCE)对增材制造和铸造Co-Cr合金金属-陶瓷结合的影响。为此,采用不同的制作工艺制备了两个实验组(n=42)的84个圆盘状(r=12 mm, h=1 mm)样品;铸造和增材制造的Co-Cr。在使用陶瓷之前,将圆盘试样分为两组(n=21):用TCE清洗的铸造组(CT)、用TCE清洗的铸造组(C)、用TCE加工和清洗的添加组(AT)、用TCE加工和未清洗的添加组(A)。将陶瓷(h=4 mm, r=6 mm)应用于圆盘试样(n=20)并测量其剪切强度(SBS)。圆盘表面形貌(n=1;采用扫描电镜(SEM)对应用TCE前后各亚组标本进行分析。结果采用单因素方差分析和Bonferroni多重比较检验(α=0.05)进行统计学分析。CT组、C组、AT组和A组的SBS有显著性差异。CT组(21.74±1.66 MPa)的SBS值明显高于C组(18.65±2.11 MPa)、AT组(19.07±1.75 MPa)和a组(18.52±1.94 MPa) (p<0.001)。综上所述,TCE的应用提高了铸造Co-Cr合金的金属-陶瓷结合。虽然结果没有统计学意义,但TCE也增加了Co-Cr合金的结合。
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