Utilization of Used Cooking Oil and Cassava Peel as Degradable Bioplastic Film

Mathivanan Loganathan, Aina Fathiah Zuhaidi, Rusyidah Mat Zin Boestami, Anis Nabilah Ahmad Hawari
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Abstract

Plastic product has become a main thing that used in human daily life. Mostly after the plastic are used, it will be a waste. Only small percentage of plastics are recycled and the rest will end up at landfills, rivers and oceans. Normally, plastics can take up to 1000 years to decompose in landfills and some will be burnt. The affect from burning the plastic waste in landfills will cause air pollution. When it burns with food waste, they will produce dioxin and furan. These elements will cause death even in small quantities when human breathe. Another harmful effect of burning plastic waste, is it can damage the ozone layer. Moreover, plastic pollution can affects all living things. At least 100 million marine mammals have died each year because of these plastic pollutions. The main objective of this research is to conduct starch extraction from cassava peels and glycerol extraction from waste cooking oil. It has been achieve during the extraction of 100g cassava peel will yield 3% of starch, while 800ml waste cooking oil yield of 5% only. The best formulation of the bioplastic obtained by controlling the ratio of carrageenan and starch at 2% and 5%. From the physical properties studies which is degradation in water and steam test. Based on the observation of degradation test, when the temperature was at 100ºC the bioplastic degrade within 1.18 minutes and at 20ºC was within 7.33 minutes. For the steam test, only at 100ºC the bioplastic start to degrade within 25minutes but for other temperature the plastic remains same. As a conclusion cassava starch can be utilized as bioplastic film, because it can dissolve when contact with water and steam. Moreover, glycerine from waste cooking oil can be used as plasticizer.
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废食用油和木薯皮作为可降解生物塑料薄膜的研究
塑料制品已成为人类日常生活中使用的主要物品。大多数情况下,塑料被使用后,它将是一种浪费。只有一小部分塑料被回收利用,其余的最终会流入垃圾填埋场、河流和海洋。通常情况下,塑料在垃圾填埋场需要长达1000年的时间才能分解,有些还会被焚烧。在垃圾填埋场燃烧塑料垃圾会造成空气污染。当它与食物垃圾一起燃烧时,它们会产生二恶英和呋喃。这些元素在人呼吸时即使是少量也会导致死亡。燃烧塑料垃圾的另一个有害影响是它会破坏臭氧层。此外,塑料污染会影响所有生物。每年至少有1亿只海洋哺乳动物死于这些塑料污染。本研究的主要目的是从木薯皮中提取淀粉,从废食用油中提取甘油。在提取过程中已经实现了100g木薯皮将得3%的淀粉,而800ml废食用油得率仅为5%。将卡拉胶与淀粉的比例分别控制在2%和5%,得到了生物塑料的最佳配方。从物理性质的研究,即在水和蒸汽试验中的降解。根据降解试验的观察,当温度为100℃时,生物塑料的降解时间为1.18 min,在20℃时,降解时间为7.33 min。对于蒸汽测试,只有在100ºC时,生物塑料在25分钟内开始降解,但在其他温度下,塑料保持不变。综上所述,木薯淀粉与水和蒸汽接触时可以溶解,因此可以用作生物塑料薄膜。此外,废食用油中的甘油还可以用作增塑剂。
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