Blending feedstock — Fresh approach in biodiesel development: Moringa and Jatropha seed oils

A. Eloka‐Eboka, F. Inambao
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引用次数: 2

Abstract

The search for improvement in the development of biomass and bio-fuels as renewable energy sources has continued for some time. Biodiesel fuels from different crude vegetable oils have been explored and evaluated as sustainable or unsustainable fuel energy sources. The fuel properties of feed stocks vary from sources, physico-chemical configuration and biological compositions and so with processes such as blending, these properties may be improved. In this study, two selected feed stocks “Moringa oleifeara” (MO) and “Jatropha curcas” (JC) seed oils and their methyl esters (biodiesel) were subjected to experimental processes in varying proportions. The s compositions were J50M50, J40M10, J30M20, J20M30, and J10M40 from crude oil samples (in situ) and: BM50J50, BM40J10, BM30J20, BM20J30 and BM10J40 from produced biodiesel by transesterification (ex-situ) using production variables and optimisation sequences. The produced results were evaluated for chemo-physical and thermal properties using ASTM and SANS standards for each specific test(s). Results disclosed the efficacy of splicing in improving specific biodiesel properties as fuels. Specific tests includes, viscosity, specific gravity, refractive index, cetane index, fatty acid composition, free and total glycerine, free fatty acid composition, flash point, pour and cloud points and calorific values. These were all higher and better than the single stock biodiesel fuels. MO biodiesel, which has proved itself an excellent fuel in the writers' previous studies having high oleic acid content (> 70%, impacted positively on JC in enhancing its potential with positive correlation at a 95% confidence level (a > 0.05) and on analysis of variation (ANOVA). This is a new approach in biodiesel development, as studies of this nature are scarce in literatures. Mixing biodiesel feedstock in situ and ex situ will no doubt give rise to new products of improved energy qualities that may bring about a much needed difference in the biodiesel industry.
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混合原料。生物柴油发展的新方法:辣木和麻疯树种子油
寻求改进作为可再生能源的生物量和生物燃料的发展已经持续了一段时间。从不同的粗植物油中提取生物柴油已经被探索和评估为可持续或不可持续的燃料能源。原料的燃料特性因来源、物理化学结构和生物成分而异,因此通过混合等工艺,这些特性可以得到改善。本研究以辣木(Moringa oleefeara)和麻疯树(Jatropha curcas)两种原料为原料,对其种子油及其甲酯(生物柴油)进行了不同比例的实验处理。利用生产变量和优化序列,分别从原油样品(原位)中得到J50M50、J40M10、J30M20、J20M30和J10M40;从生物柴油(非原位)通过酯交换反应得到BM50J50、BM40J10、BM30J20、BM20J30和BM10J40。使用ASTM和SANS标准对每个特定测试的生成结果进行化学物理和热性能评估。结果揭示了剪接在改善生物柴油作为燃料的特定性能方面的有效性。具体测试包括粘度、比重、折射率、十六烷指数、脂肪酸组成、游离甘油和总甘油、游离脂肪酸组成、闪点、倾点和浊点以及热值。这些都比单一库存生物柴油燃料更高、更好。MO生物柴油在作者之前的研究中已经证明了自己是一种优秀的燃料,油酸含量高(> 70%),在95%置信水平(> 0.05)和方差分析(ANOVA)上正相关,对JC提高其潜力有积极影响。这是生物柴油开发的新途径,因为这方面的研究在文献中很少。将生物柴油原料就地混合和非就地混合无疑会产生能源质量提高的新产品,这可能会给生物柴油行业带来急需的变化。
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