Effect of UV irradiation on photo-thermo induced nucleation of PTR glass

Ge Ziyi, Baoxing Xiong, Fan Gao, Xiang Zhang, Xiao Yuan
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Abstract

Volume Bragg gratings based on PTR glass are widely applied in high-power laser systems because of its good Bragg selection, high diffraction efficiency and high laser damage threshold. In this work, the photo-thermo induced nucleation mechanism of PTR glass was studied by comparing the absorption spectra of PTR glass before and after UV irradiation and nucleation heat treatment with Gaussian decomposition method. The results show that: the Ag0 atom formed by UV irradiation tends to be saturated at the irradiation dose of 1J/cm2 ; under the same irradiation dose, the irradiation power has no obvious effect on the number of Ag0 atoms, but it will change the the number of free electrons in glass matrix; after UV irradiation and nucleated at 460°C for 2h, the photosensitivity of PTR glass will reappear and AgBr clusters will be dominant in the silver micelles.
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紫外光照射对PTR玻璃光热诱导成核的影响
基于PTR玻璃的体积Bragg光栅由于具有良好的布拉格选择、高衍射效率和高激光损伤阈值等优点,在大功率激光系统中得到了广泛的应用。本文通过比较PTR玻璃在紫外线照射和成核热处理前后的吸收光谱,利用高斯分解法研究了PTR玻璃的光热诱导成核机理。结果表明:在辐照剂量为1J/cm2时,紫外线照射形成的Ag0原子趋于饱和;在相同辐照剂量下,辐照功率对Ag0原子数无明显影响,但会改变玻璃基体中自由电子数;经过紫外线照射,在460℃下成核2h后,PTR玻璃的光敏性恢复,银胶束中以AgBr团簇为主。
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