Radiation response of transition metals-doped lithium aluminate crystals

Y. Fujimoto, T. Yanagida, K. Kamada, J. Pejchal
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引用次数: 3

Abstract

Basic radiation response properties of lithium aluminate LiAlO2 crystals activated with transition metals like Ti, Mn and Cu were examined. When X-ray excited the crystals, intense emission peaks were observed at visible wavelength regions, they are ascribed to the Ti4+ charge transfer (Ti-doped), Mn2+ 3d5-3d5 (Mn-doped) and Cu+ 3d94s-3d10 (Cu-doped) transitions. The scintillation decay times were estimated to be about 1.8 μs (93 %) and 9.9 μs (7 %) for the Ti-doped crystal, 310 μs (96 %) and 2220 μs (4 %) for Mn-doped one, and 3.6 μs (52 %) and 19.6 μs (48 %) for Cu-doped one, respectively. In the 252Cf neutron irradiated pulse height spectra, Ti- and Cu- doped crystals showed higher light yield in comparison to that of GS20 commercial scintillator.
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过渡金属掺杂铝酸锂晶体的辐射响应
研究了过渡金属Ti、Mn和Cu活化铝酸锂LiAlO2晶体的基本辐射响应特性。当x射线激发晶体时,在可见波长区域观察到强烈的发射峰,它们归因于Ti4+电荷转移(ti掺杂),Mn2+ 3d5-3d5 (mn掺杂)和Cu+ 3d94s-3d10 (Cu掺杂)跃迁。结果表明,ti掺杂晶体的闪烁衰减时间分别为1.8 μs(93%)和9.9 μs (7%), mn掺杂晶体为310 μs(96%)和2220 μs (4%), cu掺杂晶体为3.6 μs(52%)和19.6 μs(48%)。在252Cf中子辐照的脉冲高度谱中,掺Ti和Cu晶体比GS20商用闪烁体表现出更高的光产率。
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