Intrinsic Differences on the Photodegradation Mechanisms between Pigmented and Non-Pigmented Coatings Determined by Multi-Scale Analysis

Takato Ishida, R. Kitagaki, Hideaki Hagihara, Y. Elakneswaran
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Abstract

. Multi-scale analysis of photodegradation are conducted for pigmented coating containing acrylic urethane + TiO 2 pigment and for non-pigmented coating containing only acrylic urethane. We discuss the intrinsic differences in the photodegradation mechanism between the pigmented and non-pigmented coatings and the effect of the interface between the pigment and the binder. Photo-aging tests are conducted using artificial ultraviolet (UV) irradiation under conditions of 60 °C and dry atmosphere. The results of Fourier transform infrared spectroscopy (FTIR), solvent swelling experiments, ultrasonic measurements of elastic moduli
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基于多尺度分析的有色涂料与非有色涂料光降解机理的内在差异
. 对含丙烯酸氨基甲酸酯+ tio2颜料的着色涂料和仅含丙烯酸氨基甲酸酯的非着色涂料进行了多尺度的光降解分析。我们讨论了颜料和非颜料涂层在光降解机理上的内在差异,以及颜料和粘合剂之间界面的影响。在60°C和干燥大气条件下,使用人工紫外线(UV)照射进行光老化试验。结果采用傅里叶变换红外光谱(FTIR)、溶剂溶胀实验、超声波测量弹性模量
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