Origin, Depositional Environment and Thermal Maturity of some Source Rocks from Niger Delta Basin, Nigeria

Kouadio Ke
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Abstract

Eleven (11) core samples from Agbada and Akata formations in the Niger Delta, Nigeria, were analyzed using gas chromatography-mass spectrometry to evaluate their paleodepositional conditions and source input as well as to determine their thermal maturity. The distribution of n-alkanes, isoprenoids, and biomarkers indicate a mixture (marine/terrigenous) organic matter source input for Agbada and Akata formation sediments deposited in marine environment. Low values of Phytane/nC18 (0.45 to 1.32) and Pristane/nC17 (0.37 to 1.8) indicates Marine organic matter contribution and anoxic-suboxic (Type II/III kerogens) depositional conditions of extract for Agbada and Akata Formations. The Carbon Preference Index (CPI) values for all analysed samples are slightly greater than 1.0 indicate a mixed input of marine and terrigenous organic matter deposited under relatively reducing (dysoxic) conditions. The high concentration of Oleanane in studied samples reveals that source rocks are tertiary age and belong to marine deltaic depositional environment. Moderate to higher Gammacerane index values ranging from 0.06 to 0.11, suggests water-column stratification, potentially due to hypersalinity for Isan oilfield well samples from Agbada formation. Biomarker maturity parameters suggest that the sediments have reached the early stages of hydrocarbon generation.
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尼日利亚尼日尔三角洲盆地烃源岩成因、沉积环境及热成熟度
采用气相色谱-质谱联用技术对尼日利亚尼日尔三角洲Agbada和Akata地层的11个岩心样品进行了分析,以评估其古沉积条件和源输入,并确定其热成熟度。正构烷烃、类异戊二烯和生物标志物的分布表明,Agbada组和Akata组沉积在海洋环境中,有机质输入为海相/陆源混合。Phytane/nC18(0.45 ~ 1.32)和Pristane/nC17(0.37 ~ 1.8)的低值反映了Agbada组和Akata组提取液的海相有机质贡献和缺氧-亚氧(II/III型)干酪根沉积条件。所有分析样品的碳偏好指数(CPI)值均略大于1.0,表明在相对还原(缺氧)条件下沉积的海相和陆源有机质混合输入。研究样品中齐墩烷含量高,表明烃源岩为第三纪,属于海相三角洲沉积环境。中等至较高的伽马蜡烷指数值介于0.06至0.11之间,表明水柱分层,可能是由于Isan油田Agbada地层井样的高盐度所致。生物标志物成熟度参数表明,该沉积已达到早期生烃阶段。
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