Fabrication of Bioactive Porous Ti Metal with Structure Similar to Human Cancellous Bone by Selective Laser Melting

D. Pattanayak, T. Matsushita, H. Takadama, A. Fukuda, M. Takemoto, S. Fujibayashi, K. Sasaki, N. Nishida, Toshikazu Nakamura, T. Kokubo
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引用次数: 11

Abstract

Porous titanium (Ti) metal with a structure similar to that of human cancellous bone was fabricated by selective laser melting (SLM) process. SEM observation showed that the core part of the walls of the porous body was completely melted by the laser beam and weakly bonded with small Ti particles on its surface. These Ti particles were joined with the core part by heating above 1000 °C, with remaining micro cavities on their surfaces. Tensile strength of the as-prepared solid rod was 530MPa and gradually decreased with increasing temperatures to 400MPa at 1300 °C, whereas its ductility increased with increasing temperatures. NaOH treatment formed fine network structure of sodium hydrogen titanate (SHT) on the walls of the porous Ti metal. The SHT was transformed into hydrogen titanates by HCl treatment and finally anatase and rutile by the heat treatment. Thus treated porous Ti metal formed apatite on its surface in simulated body fluid (SBF) within 3 days.
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选择性激光熔融法制备具有生物活性、结构类似人松质骨的多孔钛金属
采用选择性激光熔化(SLM)法制备了具有类似人类松质骨结构的多孔钛金属。SEM观察表明,多孔体内壁核心部分被激光束完全熔化,表面与细小的Ti颗粒结合较弱。这些Ti颗粒通过加热到1000 °C以上与核心部分结合,在其表面留下微腔。制备的固体棒的抗拉强度为530MPa,随着温度的升高逐渐降低,在1300 Â℃时达到400MPa,而塑性随温度的升高而升高。NaOH处理可在多孔钛金属表面形成细小的钛酸氢钠(SHT)网状结构。SHT经HCl处理转化为钛酸氢,最后经热处理转化为锐钛矿和金红石。因此,经过处理的多孔钛金属在模拟体液(SBF)中3天内在其表面形成磷灰石。
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