Dielectric spectra of propylene carbonate-toluene supercooled mixtures, and estimation of propylene carbonate dipolar moment at low temperature

L. Jorat, G. Noyel, J. Huck
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Abstract

The author present results from an experimental study on binary polar-nonpolar mixtures (propylene carbonate-toluene) from ambient down to their glass transition temperatures. The values of static permittivity and dielectric relaxation time obtained made it possible to estimate the temperature dependence of dipole moment and the Kirkwood correlation factor of propylene carbonate as well as the molecular relation time of toluene (or methylbenzene).<>
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碳酸丙烯-甲苯过冷混合物的介电光谱及低温下碳酸丙烯偶极矩的估算
作者介绍了二元极性-非极性混合物(碳酸丙烯-甲苯)从环境温度下降到玻璃化转变温度的实验研究结果。得到的静态介电常数和介电弛豫时间可以估计出碳酸丙烯偶极矩和柯克伍德相关系数的温度依赖性以及甲苯(或甲苯)的分子关系时间
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