UWAVE-2000 as an effective equipment for the microwave аssistant synthesis of N, N-diethyl-2-(mesitylamino)-N-benzyl-oxoethanamonium chloride – a compound with plant growth regulating activity

S. Tursynbek, K. Rafikova, A. O. Akimbek, Ye. Kamshyger, G. Jamalova, M. N. Naukanova
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Abstract

The synthesis of N,N-Diethyl-2-(mesitiylamino)-N-benzyl-oxoethanamonium chloride was carried out by N-alkylation with traditional method and using microwave and ultrasonic activation. The synthesized ionіс compound is characterized by IR, NMR 1H and 13C methods, and its growth-stimulating activity has been tested on Zea Mays L. maize seeds. The synthesis of N,N-Diethyl-2-(mesitilamino)-N-benzyl-oxoethanamonium chloride using unconventional methods such as microwave and ultrasonic activation resulted in higher yields in a shorter period of time than traditional method. The highest yield (98%) was achieved by microwave activation of UWAVE-2000 in a very short time, while in the classical caseit was lower and the reaction time was twenty-four times longer. The synthesized ionic compound positively influenced the germination and growth energy of maize seeds. In samples treated with solution N,N-Diethyl-2-(mesitylamino)-N-benzyl-oxoethanaminium chloride of mould lesions was not so many, so, the treatment of maize seeds with trimecaine benzyl chloride not only stimulates the plant growth, but also prevent fungi mould formation.
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UWAVE-2000作为微波辅助合成具有植物生长调节活性的化合物N, N-二乙基-2-(甲三氨基)-N-苄基-氧乙胺氯铵的有效设备
采用传统的N,N-二乙基-2-(甲酰基氨基)-N-苄基-氧乙胺氯铵,通过N-烷基化反应,微波和超声波活化合成了N,N-二乙基-2-(甲酰基氨基)-N-苄基-氧乙胺氯铵。通过IR、NMR 1H和13C等方法对所合成的离子化合物进行了表征,并对其在玉米种子上的促生长活性进行了测试。采用微波和超声活化等非常规方法合成N,N-二乙基-2-(美西tilamino)-N-苄基-氧乙胺氯铵,比传统方法在更短的时间内获得了更高的收率。微波活化UWAVE-2000在很短的时间内获得了最高的收率(98%),而经典活化法的收率较低,反应时间长24倍。合成的离子化合物对玉米种子的发芽率和生长能有积极的影响。在N溶液处理的样品中,N-二乙基-2-(甲三胺)-N-苄基-氧乙胺氯化铵的霉菌病变较少,因此,三曲梅碱氯化苄处理玉米种子不仅能促进植物生长,还能防止真菌霉菌的形成。
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