Phelipe Matheus Moraes Calvalcante , Renato Luiz da Silva , Jucleiton José Rufino de Freitas , Juliano Carlo Rufino de Freitas , João Rufino de Freitas Filho
{"title":"Proposta de preparação e caracterização de ésteres: um experimento de análise orgânica na graduação","authors":"Phelipe Matheus Moraes Calvalcante , Renato Luiz da Silva , Jucleiton José Rufino de Freitas , Juliano Carlo Rufino de Freitas , João Rufino de Freitas Filho","doi":"10.1016/j.eq.2015.07.003","DOIUrl":null,"url":null,"abstract":"<div><p>Esters consist in one of the classes of chemical substances widely found in nature. Some esters of low molecular weight tend to have a pleasant flavor and therefore are widely used by food and drinks industries. The esters can be synthesized by the reaction between a carboxylate anion and an alkyl halide, or by Fischer esterification reaction. Industrially, this last reaction is one of the main procedures for the esters synthesis, and according this work, a simple experiment about this specific obtaining method is described and proposed for undergraduate discipline of organic analysis. The preparation of alkyl levulinate and lactate, from levulinic acid and/or lactic acid, is carried out in laboratory, easily, requiring three periods of four hours and is useful for chemistry teaching.</p></div>","PeriodicalId":39011,"journal":{"name":"Educacion Quimica","volume":"26 4","pages":"Pages 319-329"},"PeriodicalIF":0.0000,"publicationDate":"2015-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.eq.2015.07.003","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Educacion Quimica","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0187893X15000531","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Social Sciences","Score":null,"Total":0}
引用次数: 1
Abstract
Esters consist in one of the classes of chemical substances widely found in nature. Some esters of low molecular weight tend to have a pleasant flavor and therefore are widely used by food and drinks industries. The esters can be synthesized by the reaction between a carboxylate anion and an alkyl halide, or by Fischer esterification reaction. Industrially, this last reaction is one of the main procedures for the esters synthesis, and according this work, a simple experiment about this specific obtaining method is described and proposed for undergraduate discipline of organic analysis. The preparation of alkyl levulinate and lactate, from levulinic acid and/or lactic acid, is carried out in laboratory, easily, requiring three periods of four hours and is useful for chemistry teaching.