The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell

Ho‐Young Jung, Min‐Woo Kim, Jinho Lim, J. Choi, S. Roh
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引用次数: 2

Abstract

Abstract Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPo nt’s Nafion which is a commercial polymer electrolyte membrane has high permeabili ty, high cost, and decreasing proton conductivity and dimensional stability over 80°C. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer elect rolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane’s water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.
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sPEEK/sGO复合膜中sGO含量对一体化再生燃料电池的影响
单体再生燃料电池用聚合物电解质膜要求高质子导电性、高尺寸稳定性、低渗透性和低成本。然而,杜邦公司的Nafion是一种商用聚合物电解质膜,具有高渗透性,高成本,并且在80°C以上质子电导率和尺寸稳定性下降。为了解决这些问题,选择低成本的烃类聚合物磺化聚醚醚酮(sPEEK)作为基质聚合物制备聚合物电解质膜。此外,通过引入磺化氧化石墨烯(sGO),制备了质子导电性和尺寸稳定性均有所提高的复合膜。通过考察膜的含水量、尺寸稳定性、质子电导率和形貌,分析了聚合物电解质膜的基本性质。通过电池试验研究了sPEEK/sGO复合膜在单体再生燃料电池上应用的可能性。
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