Dielectric relaxation and resonance spectra of ferroelectric polyamide 11

P. Frubing, A. Kremmer, J. Ganster, P. Pissis, R. Gerhard-Multhaupt
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引用次数: 2

Abstract

Ferroelectric polyamide 11 films were prepared by melt-quenching, cold-drawing and electrical poling. Ferroelectricity was checked by dielectric-hysteresis measurements. Dielectric spectroscopy was applied for determining piezoelectric constants from thickness-extension resonances as well as for investigating conformational changes due to quenching, stretching and electrical poling. A remanent polarisation of up to 35 mC/m/sup 2/, a coercive field of 75 MV/m and a piezoelectric d/sub 33/ coefficient of 2.7 pC/N were obtained. In the ferroelectric film, the dielectric /spl alpha/ relaxation is suppressed whereas the /spl beta/ relaxation is enhanced.
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铁电聚酰胺11的介电弛豫和共振谱
采用熔淬、冷拔和电极法制备了铁电聚酰胺11薄膜。通过介电滞后测量来检验铁电性。介电光谱用于测定压电常数从厚度扩展共振,以及研究构象变化由于淬火,拉伸和电极化。得到了残余极化高达35 mC/m/sup 2/,矫顽力场为75 MV/m,压电d/sub 33/系数为2.7 pC/N。在铁电薄膜中,介电/spl α /弛豫被抑制,而/spl β /弛豫被增强。
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