Life Cycle Assessment of Electrospun Cellulose-Based Nanocomposite Membrane Fabrication

Nasrin Attari, R. Hausler
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Abstract

- Polymer nanocomposite membrane is an innovative and promising approach with a broad spectrum of potential applications in filtration processes. It is used to selectively separate molecules and ions. A comprehensive understanding of its environmental impacts, covering the life cycle of the used materials and the fabrication process, is crucial for its long-term sustainable success. This research aims to elaborate and implement a decision-making tool for greener membrane fabrication process. The environmental impacts of synthesizing one batch of Nanocomposite cellulose nanofibrils/cellulose acetate membrane using 50 gr polymer dope solution by electrospinning technique was determined based on a life cycle assessment methodology. The eco-sufficiency and sustainability of the electrospinning method were evaluated through a cradle-to-gate life cycle assessment (LCA) adopting the Cumulative Energy Demand (CED), and IMPACT2002+ impact assessment methods. According to CED assessment, the majority of energy consumed during electrospun membrane synthesis, amounting to 382 MJ, was consumed by the production of cellulose nanofibers. This is related to non-renewable fossil energy consumed in Ethanol production. As per IMPACT2002+ impact assessment, cellulose acetate and cellulose nanofiber manufacturing, and medium voltage electricity are the main contributors to the overall midpoint environmental effects.
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电纺纤维素基纳米复合膜的生命周期评价
聚合物纳米复合膜是一种创新和有前途的方法,在过滤过程中具有广泛的潜在应用。它被用来选择性地分离分子和离子。全面了解其对环境的影响,包括使用材料的生命周期和制造过程,对其长期可持续的成功至关重要。本研究旨在为更环保的膜制造过程设计并实施决策工具。采用生命周期评价方法,对静电纺丝法制备一批纳米复合纤维素/醋酸纤维素膜的环境影响进行了研究。采用累积能源需求(CED)和IMPACT2002+影响评估方法,通过从摇篮到门的生命周期评估(LCA)对静电纺丝方法的生态充分性和可持续性进行了评价。根据CED评估,电纺膜合成过程中消耗的大部分能量,约为382兆焦耳,用于生产纤维素纳米纤维。这与乙醇生产中消耗的不可再生化石能源有关。根据IMPACT2002+影响评估,醋酸纤维素和纤维素纳米纤维制造以及中压电力是造成整体中点环境影响的主要因素。
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