Dielectric relaxation behaviour of electrically (AC) aged polyethylene in humid environment

P. Scarpa, A. Svatik, D. Das-Gupta
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Abstract

The dielectric spectroscopy of the unaged and AC aged (6 kV/mm, 2.5 kHz, 0.1N NaCl, 69 hours) LDPE samples with three different experimental conditions (i.e., at room temperature, at room temperature after additional DC poling at 70/spl deg/C with 2 kV/mm for 1 hour followed by cooling down to room temperature in the presence of the field, and at 70/spl deg/C), are presented. It is shown that a parallel combination of the "universal relaxation law" and "low frequency dispersion" relaxation can account for the observed behaviour. The observed changes in the low frequency range (10/sup -5/Hz to 10/sup -2/Hz) appear to be most significant regarding the electrical ageing.<>
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电老化聚乙烯在潮湿环境中的介电弛豫行为
给出了三种不同实验条件下(室温下、在70/spl℃、2 kV/mm条件下外加直流极化1小时后冷却至室温下和在70/spl℃条件下)未老化和交流老化(6 kV/mm、2.5 kHz、0.1N NaCl、69 h) LDPE样品的介电光谱。结果表明,“普遍松弛定律”和“低频色散”松弛的平行组合可以解释所观察到的行为。观察到的低频范围(10/sup -5/Hz至10/sup -2/Hz)的变化似乎对电老化最为显著。
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